Synchronous Scan and Excitation-Emission Matrix Fluorescence Spectroscopy of Water-Soluble Organic Compounds in Atmospheric Aerosols     

Regina M.B.O. Duarte  Casimiro A. Pio  Armando C. Duarte 《Journal of Atmospheric Chemistry》2004,48(2):157-171

Three-dimensional excitation–emission matrix (EEM) fluorescence spectra of water-soluble organic compounds (WSOC) from aerosol samples were measured and compared with those reported in the literature for natural dissolved organic matter. The EEM profiles of the WSOC presented three characteristic excitation/emission (_Exc/_Em) peaks: 240/405 nm, 310/405 nm and 280/340 nm. The fluorescence intensities at _Exc/_Em240/405 nm and _Exc/_Em310/405 nm are located at wavelengths shorter than those reported for aquatic humic substances, indicating a smaller content of both aromatic structures and condensed unsaturated bond systems in the WSOC fraction. The EEM profiles of fractions obtained by the isolation procedure of the WSOC by the XAD resins showed that a fractionation has occurred and the XAD-8 eluate is highly representative of the total WSOC of collected aerosol. Synchronous scan spectra were more detailed than conventional fluorescence emission spectra, appearing more suitable for studying multicomponent samples such as the WSOC from atmospheric aerosols.  相似文献   

Convection in a rotating deep compressible spherical shell: Application to the Sun     

Gaetano Belvedere  Lucio Paternò 《Solar physics》1977,54(2):289-312

In this paper we study the interaction of rotation with convection in a deep compressible spherical shell as the Sun's convection zone. We examine how the energy transport and the large scale motions can be affected by rotation. In particular we study how a large scale meridional circulation can give rise to variations of angular velocity with latitude and depth.It is assumed that the energy transport is only due to convection and that the mixing-length theory gives an adequate representation of it. Furthermore we assume that rotation acts as a perturbation of the turbulent convective flux through its transport coefficient.The equations involved in the model are integrated numerically in the limit of large viscosity and slow rotation. After having expanded all physical quantities to the first order in terms of Legendre polynomials, the fitting with the observed solar differential rotation gives the expansion parameter, which represents the coupling constant between rotation and convection.The results show a three-cell circulation extending from the poles to the equator. The first one is located in the lower half of the convection zone with the fluid rising at the equator and sinking at the poles. In the second one the direction of the motion is reversed while the third one, located in a thin upper layer, shows the same characteristics of the first one. The meridional velocities at the surface are directed towards the poles and are about 20 cm s^-1. In the other cells the meridional velocities are typically of a few cm s^-1 while the radial velocities are of the order of a few tenths of cm s^-1.The heat flux relative variation at the surface is about 10^-4 (3 × 10^-3 at the bottom) with a polar excess. The temperature variation at the surface is of the same order, with an equatorial excess however. The convection seems to be stabilized stronger at the equator. The angular velocity increases inwards and varies about 6% between the surface and the bottom of the convection zone.An attempt is made for explaining the picture which emerges. In particular the negligible flux and temperature variations at the surface are explained in terms of equalization by the particular structure of the latitudinal flow. This configuration of large scale circulation is attributed to the high stratification of the convection zone with depth.  相似文献   

Voyager disk-integrated photometry of Io     

Damon P. Simonelli  Joseph Veverka 《Icarus》1984,59(3):406-425

Voyager full-disk images of Io, available at solar phase angle of α = 2?29° and 101?159°, allow comparisons of the satellite's near-opposition photometric behavior with Earth-based results and the determination of the phase curve out to very high phase angles. The near-opposition data were reduced iteratively for self-consistent phase and rotation curves in each Voyager filter; the resulting phase coefficients, geometric albedos, and rotational lightcurves are consistent with Earth-based findings, except for a previously noted tendency for Voyager to yield somewhat redder spectral information. The derived near-opposition phase coefficients, ranging between 0.016 and 0.024 mag/ deg, decrease with increasing wavelength, a trend weakly noted in some Earth-based observations. The full, α = 2?159° phase curves allow the first direct determination of the phase integral of Io at several wavelengths: q rises from ≈0.7 in the ultraviolet to ≈0.8 in the orange. Combination of the Voyager phase integrals with Earth-based albedo information leads to a best estimate of the bolometric Bond albedo of 0.50 ± 0.10, a value consistent with, but slightly below, previous estimates.  相似文献   

Petrogenesis of the early Cretaceous Valle Chico igneous complex (SE Uruguay): Relationships with Paraná–Etendeka magmatism     

Michele Lustrino  Leone Melluso  Pietro Brotzu  Celso B. Gomes  Lucio Morbidelli  Rossana Muzio  Excelso Ruberti  Colombo C.G. Tassinari 《Lithos》2005,82(3-4):407-434

The early Cretaceous (130 Ma) igneous complex of Valle Chico (SE Uruguay) is made up of felsic plutonic and subordinate volcanic rocks and dykes cropping out over an area of about 250 km². This complex is strictly linked with the formation of the Paraná–Etendeka Igneous Province and the first stages of the South Atlantic Ocean rifting. The plutonic rocks range from quartz-monzonite to syenite, quartz-syenite and granite. The volcanic rocks and the dykes range from quartz-latite to trachyte and rhyolite; no substantial differences in term of chemical composition have been found between plutonic and volcanic rocks. Only a sample of basaltic composition (with tholeiitic affinity) has been sampled associated with the felsic rocks. The Agpaitic Index of the Valle Chico felsic rocks range from 0.72 to 1.34, with the peralkaline terms confined in the most evolved samples (SiO₂>65 wt.%). Initial ⁸⁷Sr/⁸⁶Sr₍₁₃₀₎ of the felsic rocks range from 0.7046 to 0.7201, but the range of ⁸⁷Sr/⁸⁶Sr of low-Rb/Sr samples cluster at 0.7083; ¹⁴³Nd/¹⁴⁴Nd₍₁₃₀₎ ratios range from 0.5121 (syenite) to 0.5117 (granite). The tholeiitic basalt show more depleted isotopic compositions (⁸⁷Sr/⁸⁶Sr₍₁₃₀₎=0.7061; ¹⁴³Nd/¹⁴⁴Nd₍₁₃₀₎=0.5122), and plots in the field of other early Cretaceous low-Ti basaltic rocks of SE Uruguay. The radiogenic Sr and unradiogenic Nd of the Valle Chico felsic rocks require involvement of lower crustal material in their genesis either as melt contaminant or as protolith (crustal anatexis). In particular, most of the Valle Chico (VC) felsic rocks define a near-vertical array in Sr–Nd isotopic spaces, pointing toward classical EMI-type composition; this feature is considered to reflect a lower crust involvement as observed for other mafic and felsic rocks of the Paraná–Etendeka Igneous Province. Decompression melting of the lower crust related to Gondwana continental rifting before the opening of the South Atlantic Ocean or the presence of thermal anomalies related to the Tristan plume may have induced the lower crust to partially melt. Alternative hypothesis considers contamination of upper mantle by a mafic/ultramafic keel composed of lower crust and uppermost mantle after delamination and detachment processes. This interaction may have occurred after the continent–continent collision during the last stages of the Panafrican Orogeny. This “lower crust” model does not exclude active involvement of upper crust as contaminant, necessary to explain the strongly radiogenic ⁸⁷Sr/⁸⁶Sr₍₁₃₀₎ isotopic composition of some VC SiO₂-rich rocks. Mineralogical (sporadic presence of pigeonite, Ca–Na and Na clinopyroxene, calcic- and calco-sodic amphibole) and geochemical evidences (major and trace element as well as Sr–Nd isotopic similarities with the felsic early Cretaceous volcanic rocks of the Arequita Formation in SE Uruguay) allow us to propose for the VC rocks a transitional rock series (the most abundant rock types are of syenitic/trachytic composition) preferentially evolving towards SiO₂-oversaturated compositions (granite/rhyolite) also with a strong upper crustal contribution as melt contaminant. This conclusion is in contrast with previous studies according which the VC complex had clear alkaline affinity. Many similarities between VC and the coeval Paresis granitoids (Etendeka, Namibia) are evidenced in this paper. The genetic similarities between VC and the rhyolites (s.l.) of SE Uruguay may find counterparts with the genetic link existing between the early Cretaceous tholeiitic-alkaline Messum complex and the quartz latites (s.l.) of the Awahab Formation (Etendeka region, Namibia).  相似文献   

Reliability of water content estimation by profile probe and its effect on slope stability     

Lucio Di Matteo  Cristina Pauselli  Daniela Valigi  Maurizio Ercoli  Mauro Rossi  Giacomo Guerra  Costanza Cambi  Remo Ricco  Giuseppe Vinti 《Landslides》2018,15(1):173-180

Shallow landslide failures are distributed worldwide and cause economic losses and fatalities. A proper evaluation of the possible occurrence of shallow landslides requires reliable characterization of water content. Volumetric water content (θ) is commonly estimated using dielectric sensors, which use manufacturers’ calibration curves developed for specific soil types. In this study, we present the experimental results achieved during a laboratory calibration of a capacitance probe (PR2/6 probe), tested on two sandy soils widely outcropping in Central Italy. The proposed equations demonstrate a more reliable estimation of θ with respect to the generalized soil equation provided by the manufacturer, which overestimates θ by up to 10 percentage points. Such overestimation could affect the evaluation of suction stress in partially saturated shallow soils affecting the slope stability analysis. Although the use of θ from correct calibration equations provides less precautionary factor of safety values, a reliable evaluation of the soil moisture condition is fundamental when mapping and predicting the spatial and temporal occurrence of shallow landslides. The use of the PR2/6 probe with the appropriate soil calibration equations in early warning monitoring systems will provide a more reliable forecast, minimizing the number of false alarms.  相似文献   

Differential rotation set up by latitude-dependent heat transport     

Gaetano Belvedere  Lucio Paterno  Michael Stix 《地球物理与天体物理流体动力学》2013,107(1):209-224

Abstract

Models of differentially rotating compressible deep spherical shells are computed according to the method of Belvedere and Paternò (1977): the heat transport is entirely convective, small-scale motions are parametrized by a thermal diffusivity and a kinematic viscosity, and the limit of slow rotation and large viscosity is considered.

In order to adapt the resulting differential rotation to the observed equatorial acceleration of the Sun, the heat transport must be more effective in the vicinity of the equator. In all models the latitude dependence of the transport coefficient induces meridional circulation in the form of a large cell, with rising material at high latitudes and sinking material near the equator. On top of this cell, one or two thin countercells develop in a minority of cases. Large pole-equator temperature differences and meridonal velocities at the surface are obtained when the Prandtl number is 1. But values of, say, 1/10 are sufficiently small to allow the models to be applied to the Sun. In general an angular velocity increasing with depth is found, and the surfaces of constant angular velocity are inclined towards greater depth and higher latitude.  相似文献   

Iron speciation in minerals and glasses probed by $$\hbox{M}_{2/3}$$-edge X-ray Raman scattering spectroscopy     

A.?NyrowEmail author  C.?Sternemann  M.?Wilke  R.?A.?Gordon  K.?Mende  H.?Yava?  L.?Simonelli  N.?Hiraoka  Ch.?J.?Sahle  S.?Huotari  G.?B.?Andreozzi  A.?B.?Woodland  M.?Tolan  J.?S.?Tse 《Contributions to Mineralogy and Petrology》2014,167(5):1012

We present a spectroscopic study of the iron \(\hbox{M}_{2/3}\)-edge for several minerals and compounds to reveal information about the oxidation state and the local coordination of iron. We describe a novel approach to probe the iron \(\hbox{M}_{2/3}\)-edge bulk sensitively using X-ray Raman scattering. Significant changes in the onset and shape of the Fe \(\hbox{M}_{2/3}\)-edge were observed on ferrous and ferric model compounds with Fe in octahedral and tetrahedral coordination. Simulation of the spectra is possible using an atomic multiplet code, which potentially allows determination of, e.g., crystal-field parameters in a quantitative manner. A protocol is discussed for determination of the Fe oxidation state in compounds by linear combination of spectra of ferric and ferrous end members. The presented results demonstrate the capabilities of Fe \(\hbox{M}_{2/3}\)-edge spectroscopy by X-ray Raman scattering to extract information on the ratio of trivalent to total iron \(\hbox{Fe}^{3+}/\sum \hbox{Fe}\) and local coordination. As X-ray Raman scattering is performed with hard X-rays, this approach is suitable for in situ experiments at high pressure and temperature. It thus may provide indispensable information on oxidation state, electronic structure and local structure of materials that are important for physical and chemical processes of the deep Earth.  相似文献   

Groundwater Quality: Analysis of Its Temporal and Spatial Variability in a Karst Aquifer   总被引：2，自引：0，他引：2       下载免费PDF全文

Roger Pacheco Castro  Julia Pacheco Ávila  Ming Ye  Armando Cabrera Sansores 《Ground water》2018,56(1):62-72

This study develops an approach based on hierarchical cluster analysis for investigating the spatial and temporal variation of water quality governing processes. The water quality data used in this study were collected in the karst aquifer of Yucatan, Mexico, the only source of drinking water for a population of nearly two million people. Hierarchical cluster analysis was applied to the quality data of all the sampling periods lumped together. This was motivated by the observation that, if water quality does not vary significantly in time, two samples from the same sampling site will belong to the same cluster. The resulting distribution maps of clusters and box‐plots of the major chemical components reveal the spatial and temporal variability of groundwater quality. Principal component analysis was used to verify the results of cluster analysis and to derive the variables that explained most of the variation of the groundwater quality data. Results of this work increase the knowledge about how precipitation and human contamination impact groundwater quality in Yucatan. Spatial variability of groundwater quality in the study area is caused by: a) seawater intrusion and groundwater rich in sulfates at the west and in the coast, b) water rock interactions and the average annual precipitation at the middle and east zones respectively, and c) human contamination present in two localized zones. Changes in the amount and distribution of precipitation cause temporal variation by diluting groundwater in the aquifer. This approach allows to analyze the variation of groundwater quality controlling processes efficiently and simultaneously.  相似文献   

Fluorescence as a Tool for Tracing the Organic Contamination from Pulp Mill Effluents in Surface Waters     

Eduarda B. H. Santos  Olga M. S. Filipe  Regina M. B. O. Duarte  Helena Pinto  Armando C. Duarte 《洁净——土壤、空气、水》2001,28(7):364-371

Three‐dimensional fluorescence spectra of water samples from an eucalyptus bleached kraft pulp mill and from a river, upstream and downstream of the discharge of the effluent, revealed the existence of a peak at δ_exc = 280 nm and δ_em = 340 nm Δδ = 60 nm), characteristic of effluentπs organic matter. Humic substances were isolated from the effluent by sequential adsorption onto resins XAD‐8 and XAD‐4 in series. Their synchronous fluorescence spectra with Δδ = 60 nm do also exhibit an intense signal at δ_exc = 280 nm (≈ 300 nm in the humic acid fraction). The peak is absent in the spectra of humic substances isolated from a non‐polluted site of the river, but it is clearly seen in the spectra of the humic substances from a site downstream of the discharge of the effluent. Synchronous fluorescence spectra (Δδ = 60 nm) of water samples from the river and its lagoon were recorded and revealed to be an easy and fast way of tracing the organic contamination from the effluent.  相似文献   

Differences between Humic Substances from Riverine,Estuarine, and Marine Environments Observed by Fluorescence Spectroscopy     

Valdemar I. Esteves  Armando C. Duarte 《洁净——土壤、空气、水》2001,28(7):359-363

Sixteen samples of fulvic acids and XAD‐4 fractions of riverine, estuarine, coastal, and open ocean origin have been studied by emission and synchronous molecular fluorescence spectroscopy. Certain features of the molecular fluorescence are related to the nature, the content, and the origin of those aquatic humic substances (HS). Riverine HS appear several times richer in fluorophores than marine HS, which can be well observed by emission fluorescence spectroscopy. Synchronous‐scan spectra of fulvic acids and of XAD‐4 fractions from the aquatic environments studied, emphasized the quality differences of their fluorophores. These features are useful as tracers of humic substances related with their natural environment source or even with their anthropogenic origin.  相似文献